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Investigation of the single plant source bee glue type originating from Southern Australia resulted in the isolation and structure elucidation of major serrulatane diterpenes, novel 7,8,trihydroxyserrulatene 1 , along with its oxidized product, 5,epoxyserrulaten-7,8-dione 3 and known 18 RS -5,epoxyserrulaten-8,diol 2. Exploration into the botanical origin revealed Myoporum insulare R. Br, as the plant source of the bee glue materials.
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Jungjohann, Peony C. The second catechol oxidation in the last stage gives compound 3. From the main skeleton of the compounds, serrulatane, plants of the genus, EremophilaScrophulariaceae family, were considered as possible sources.
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Structure elucidation and botanical characterization of diterpenes from a specific type of bee glue a subsidiary of americhoke.
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